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dc.contributor.authorKusmiyati
dc.date.accessioned2013-01-21T08:27:54Z
dc.date.available2013-01-21T08:27:54Z
dc.date.issued2009-10
dc.identifier.citationAgarwal, A. K. (2007). “Biofuels (Alcohol and Biodiesel) Applications as Fuels for Internal Combustions Engines”. Progress in Energy and Combustión Science. 33. 233-271. Agreda, V. H. and Parin, L. R. (1990). “High Purity Methyl Acetat via Reactive Distillation”. Chemical Engineering Progress. 86 (2). 40-46. Altiokka, M. R. and Citak, A. (2003). “Kinetics Study of Esterifikasi of Acetic Acid with Isobutanol in the Presence of Amberlite Catalyst”. Applied Catalysis A General. 230. 141-148. Araujo, L. R. R., Scofielda, C. F., Pasturaa, N. M. R. and Gonzalez, W. A. (2006). “H3PO4/Al2O3 Catalysts: Characterization and Catalytic Evaluation of Oleic Acid Conversion to Biofuels and Biolubricant”. Materials Research. 9. 181-184. Bailey’s Industrial Oil and Fat Product. (1996).5th ed. Edited by Y.H. Hui, Wiley-Interscience Publication, USA. Bart, H. J., Reidetschlager, J., Schatka, K. and Lehmann, A. (1994). “Kinetics of Esterification Levulinic Acid with n-Butanol by Homogeneous Catalysis”. Industrial Engineering Chemical Research. 33. 21-25. Bhatia, S., Mohamed, A. R., Ahmad, A. L., Chin, Y. (2006). “Production Of Isopropyl Palmitate In A Catalytic Distillation Column: Comparison Between Experimental and Simulation Studies”. Computers and Chemical Engineering. 31. 1187-1198. Bock, H., Wozny, G and Gutsche, B. (1997). “Design and Control of a Reaction Distillation Column Including the Recovery System”. Chemical Engineering and Processing. 36. 101-109. Calvar, N., Gonzales, B., Dominguez, A. (2006). “Esterification Of Acetic Acid With Ethanol: Reaction Kinetics and Operation In A Packed Bed Reactive Distillation Column”. Chemical Engineering Process. xxx-xxx. 1-7. Chung, K. H., Chang, D. R. and Park, G. B. (2008). “Removal of Free Fatty Acid in Waste Frying Oil by Esterification With Methanol on Zeolite Catalysts”. Bioresource Technology. 99. 7438-7443.en_US
dc.identifier.urihttp://hdl.handle.net/11617/2569
dc.description.abstractBiodiesel is an alternative diesel fuel that is produced from vegetable oils and animal fats. Generally, it is formed by transesterification reaction of triglycerides in the vegetable oil or animal fat with an alcohol. In this work, esterification reaction was carried out using oleic acid, methanol and sulphuric acid as a catalyst by reactive distillation method. In order to determine the best conditions for biodiesel production by reactive distillation, the experiments were carried out at different temperature (1000C, 1200C, 1500C and 1800C) using methanol/oleic acid molar ratios (1:1, 5:1, 6:1, 7:1, 8:1), catalyst/ oleic acid molar ratios (0.5%wt, 1%wt, 1.5%wt and 2%wt) and reaction times (15, 30, 45, 60, 75 and 90 minutes). Result show that at temperature 1800C, methanol/ oleic acid molar ratio of 8:1, amount of catalyst 1% for 90 minute reaction time gives the highest conversion of oleic acid above 0.9571. Biodiesel product from oleic acid was analysed by ASTM (American Standard for Testing Material). The results show that the biodiesel produced has the quality required to be a diesel substitute.en_US
dc.description.sponsorshipHIBAH FUNDAMENTAL DIKTIen_US
dc.publisherLPPM UMSen_US
dc.subjectBiodieselen_US
dc.subjectreactive distillationen_US
dc.subjectoleic aciden_US
dc.subjectesterificationen_US
dc.titlePENGEMBANGAN REAKSI ESTERIFIKASI ASAM OLEAT DAN METANOL DENGAN METODE REAKTIF DISTILASIen_US
dc.typeThesisen_US


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