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dc.contributor.authorMujiburohman, Muhammad
dc.contributor.authorHidayati, Nur
dc.contributor.authorPurnama, Herry
dc.contributor.authorKurniawan, Vendi
dc.date.accessioned2014-12-03T09:02:31Z
dc.date.available2014-12-03T09:02:31Z
dc.date.issued2014-12-04
dc.identifier.citation[1] J.K. Lee, W. Li, A. Manthiram, “Poly(arylene ether sulfone)s containing pendant sulfonic acid groups as membrane materials for direct methanol fuel cells,” Journal of Membranes Science, vol. 330, pp.73-79, 2009. [2] T. H. Young, et al., “Improvement of electrochemical performances of sulfonated poly(arylene ether sulfone) via incorporation of sulfonates poly(arylene ether benzimidazole),” Journal of Power Source, vol. 175, pp. 724-731, 2008. [3] W. Sheng, et al. “Sulfonated poly(ether sulfones) (sPES)/ boron phosphate (BPO4) composite membranes for high temperature proton exchange membrane fuel cells,” International Journal of Hydrogen Energy , vol. 34, pp. 8982-8991, 2009. [4] V. R. Gowariker, et al., ” Polimer Science,” New Delhi: New Age International,” 1986. [5] L.A. Silva, et al., ” Poly(styrene-co-acrylonitrile) based proton conductive membranes,” European Polymer Journal, vol. 17, pp. 1462- 1474, 2008. [6] M. A. Hickner, et al.,” Alternative polymer systems for Proton Exchange Membranes (PEMs),” Chemical Review vol. 104,pp. 4587- 4612, 2004. [7] V. Neburchilov, et al.,”A review of polymer electrolyte membranes for direct methanol fuel cells,” Journal of Power Sources vol. 169(2), pp. 221-238, 2007. [8] L. Li, J. Zhang, and Y. Wang,”Sulfonated poly(ether ether ketone) for direct methanol fuel cell,” Journal of Membranes Science vol. 226, pp. 159-167, 2003. [9] S. M. Javaid Zaidi,”Polimer Sulfonation-A versatile route to prepare proton-conducting membrane material for advanced technologies,” The Arabian Journal for Science and Engineering, vol. 28, pp. 183-194, 2003. [10] R. S. L. Yee, K. Zhang and B. P. Ladewig, “The effect of sulfonated Poly(ether ether Ketone) Ion Exchange Preparation Condition on membrane properties,” Membranes, vol 3, pp. 182-195, 2013. [11] R. Y. M. Huang, P. Shao, C. M. Burns, X. Feng, “Sulfonation of poly(ether ether ketone) (PEEK): kinetic study and characterization, Journal of Applied Polymer Science, vol 82, pp. 2651-2660, 2001. [12] M.H.D. Othman, A.F. Ismail, A. Mustafa, Malaysian Polimer Journal (2007) 2, 10-28. ICETIAen_US
dc.identifier.issn2407-4330
dc.identifier.urihttp://hdl.handle.net/11617/4995
dc.description.abstractA fuel cell, a device transforming directly the chemical energy into electricity through a chemical reaction, is a source of clean energy in the future. Direct Methanol Fuel Cell (DMFC), uses a proton exchange polymer electrolyte which one of the key components developed to realize the commercialization of fuel cells in transportation and portable equipment. Poly Ether Ether Ketone (PEEK) is a thermoplastic material that has a combination of physico-chemical and good mechanical properties. The introduction of sulphonic acid groups into the polymer chain is an easy strategy to improve the properties of PEEK. This research aims to study the effect of time and the temperature of sulfonation in the fabrication of sulfonated PEEK on the membrane characteristics such as water uptake, methanol permeability, Ion Exchange Capacity (IEC), degree of sulfonation and proton conductivity. The results indicated that sPEEK was potential candidate as proton conductive membrane for application of DMFC due to enhancement of proton conductivity although the methanol permeability also increases proportional with IEC or DS.en_US
dc.publisherUniversitas Muhammadiyah Surakartaen_US
dc.subjectDMFCen_US
dc.subjectfuel cellsen_US
dc.subjectsPEEKen_US
dc.subjectsulfonationen_US
dc.titleSulfonated Polyether Ether Ketone Membrane and Its Properties for Direct Methanol Fuel Cellsen_US
dc.typeArticleen_US


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